5. CHEMICAL IRRITANTS (INCLUDING TEAR GAS
AND PEPPER SPRAY)24
Description: Chemical irritants are substances that produce sensory irritation and
pain in the eyes and upper respiratory tract. The chemicals most commonly used are
CN or CS (often called tear gas) and OC/Pepper or PAVA (often called pepper spray).
Chemical irritants are delivered through handheld aerosol sprays, shoulder-worn
and backpack sprayers, hand-thrown grenades, weapon-launched projectiles and
grenades, as well as via water cannons. Handheld aerosol sprays range in size from
25ml to 500ml, and sometimes more, while shoulder-worn and backpack-style
sprayers generally have a much larger capacity and can cover a wider area. Handthrown and weapon-launched projectiles/grenades and water cannons can be used
from greater ranges and can be used to contaminate a wide area.
Intended purpose: Chemical irritants are designed to deter or disable individuals
by producing temporary but intense irritation of the eyes and upper respiratory tract.
They are frequently used in many countries in the policing of public gatherings.
Factors that determine the effects of chemical irritants include the type of chemical
agent and means of delivery used, the location and environmental conditions in
which they are used, and the concentration and quantity of irritant. Smaller, handheld sprays are intended to be used to temporarily deter or disorientate individuals,
whereas the UN bodies have stressed that means of delivery for wider areas should
24
The 1992 Chemical Weapons Convention uses the term “riot control agents”, defined as “Any chemical
not listed in a Schedule, which can produce rapidly in humans sensory irritation or disabling physical
effects which disappear within a short time following termination of exposure.” Art. II(7), 1992 Chemical
Weapons Convention. The use of this term is avoided in this resource because it is inaccurate and
pejorative to refer to all public assemblies as riots, and the term overlooks the fact that chemical irritants are also used for purposes other than crowd control.
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